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Q.

Which of the following reaction involves the liberation of energy?

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a

Na(s)Na(g)+

b

Cl2(g)2Cl(g)

c

Na(g)++Cl(g)-NaCl(s)

d

NaCl(s)Na(g)++Cl(g)-

answer is C.

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Detailed Solution

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1 Na(s)I Sublimation Na(g)II Ionization Na+(g)

I & II are endothermic

2 Cl2(g) Bond dissociation energy III2Cl(g)

III is endothermic

3 Na+(g)+Cl-(g)IVL.ENaCl(s)

IV is exothermic, lattice enthalpy is the energy released when gaseous cation and anion combine to form one mole of ionic crystal

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