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Q.

Which of the following reactions do not involve oxidation reduction?

I. 2Cs+2H2O2CsOH+H2II. 2CuI22CuI+I2III. NH4Br+KOHKBr+NH3+H2OIV. 4KCN+Fe(CN)2K4Fe(CN)6

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a

I, III

b

I,III, IV

c

III, IV

d

I, II

answer is D.

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Detailed Solution

I. CsCs1++e(Oxidation) H2O+eOH+12H2 (Reduction)

Hence, redox reaction

 II. e-+Cu2+ Cu1+(Reduction)2I I2+2e-(Oxidation)                                                            Hence, redox reaction.

III. NH4x=-3 NH3x=-3(No change in oxidation number ) Hence, reaction is not redox 

IV. No change in the oxidation number of either Fe2+ or CN in both reactant and product; hence, not redox reaction

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Which of the following reactions do not involve oxidation reduction?I. 2Cs+2H2O⟶2CsOH+H2II. 2CuI2⟶2CuI+I2III. NH4Br+KOH⟶KBr+NH3+H2OIV. 4KCN+Fe(CN)2⟶K4Fe(CN)6