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Q.

Which of the following reactions is a decomposition redox reaction? 

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a

N2(g)→O2(g)+2NO(g)

b

P4(s))+3OH-(aq)+H2O(l)→PH3(g)+3H2PO-2(aq)

c

2Pb(NO3)2(s)→2PbO(S)+4NO2(g)+O2(g)

d

Cl2(g) + 2OH(aq) → ClO(aq) + Cl(aq) + 4H2O(ℓ) 

answer is A.

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Detailed Solution

2PbNO32(s)Δ2PbO(s)+4NO2(g)+O2(g)
In redox reaction, oxidation number changes.
(1) Oxidation state of N is decreasing from +5 to +4 .
Oxidation state of N is increasing from -2 to zero.
(2) It is redox synthesis reaction.
N:0 to +2
O: 0 to -2
(3), (4) Disproportionation reaction

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