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Q.

Which of the following reacts with NaOH to produce on salt of carboxylic acid and an alcohol ?

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a

HCHO       

b

CH3COOH

c

CH3CH2COOH

d

C6H5COOH

answer is A.

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Detailed Solution

Aldehyde undergoes Cannizzaro reaction and forms both acid and alcohol when reacts with base. For example, benzaldehyde forms sodium benzoate (salt of carboxylic acid) and benzyl alcohol when reacts with 50% of NaOH.

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