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Q.

Which of the following reagents can be used to distinguish between propene and propyne ?

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a

Ammoniacal CuCl2

b

Grignard reagent

c

Ammoniacal AgNO3.

d

Lucas reagent

answer is Ü.

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Detailed Solution

Propyne has acidic hydrogen but propene does not. Therefore, propyne reacts with Grignard reagent to evolve alkane (RH),  with AgNO3  to give white ppt. of silver propynide and with ammoniacal solution of CuCl  to from red ppt. of copper propynide.

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