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Q.

Which of the following reagents cannot distinguish between glucose and fructose ?

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a

Tollens’ reagent

b

All of these

c

Fehling’s solution

d

Benedict’s solution

answer is D.

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Detailed Solution

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The reason is that in the basic or acidic medium fructose will rearange to aldose and give the test, The detail reason is as 

Lobry De Braun–Alberda van Elkenstein re-arrangement reaction is the base or acid catalyzed re-arrangement of an aldose into the ketose isomer, into a mixture of monosaccharides. The intermediate is a tautomeric ene-diol. Which is the main reason for isomerization.

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