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Which of the following reagents converts both acetaldehyde and acetone to alkanes?

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$N i / H_{2}$

$Z n - H g / H C l$

$L i A l H_{4}$

$N a O H / I_{2}$

answer is D.

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Detailed Solution

The acetaldehyde and acetone are converted to corresponding alkane with the help of Ziegler-Natta reagent ( $Z n - H g / H C l$ ) in presence of strong acid like $H C l$ .

The reaction is also known as Clemensson's reduction. It converts carbonyl group to methylene group.

Acetaldehyde Ethane

Question Image

Acetone Propane

Hence, the correct answer is option (D) $Z n - H g / H C l .$

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