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Q.

Which of the following reduction are actually employed in commercial extraction of metals?

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a

Fe2O3+2AlAl2O3+2Fe

b

Cr2O3+2AlAl2O3+2Cr

c

2NaAu(CN)2+ZnNa2Zn(CN)4+2Au

d

Cu2S+2CuO6Cu+SO2

answer is B, C, D.

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Detailed Solution

Commercial chromium extraction involves aluminum reduction. The reaction is having follows

Cr2O3+2Al2Cr+Al2O3

By heating it in the presence of a diluted solution of  NaCN and O2 Au2S is leached

The following reaction will obtain

Au2S+4NaCN4Na+2Au(CN)22+S2

Gold is produced by a displacement process in which the cyanide molecule is treated with zinc

The reaction is having follows,

2NaAu(CN)2+ZnZn(CN)42+2Au

Hence, options B C and D are correct.

 

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