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Q.

Which of the following represent(s) van’t Hoff equation ?

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a

d(lnK)/dT=ΔH/RT2

b

K=AeEa/RT

c

d(lnK)/dT=ΔH/RT2

d

K=AeΔH/RT

answer is B, C.

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Detailed Solution

K = Ae-ΔH/RT. Taking logarithm on both sides, we get in K = ln ΔΔHRT 

Differentiating w.r.t. T, we get  d ln KdT = ΔHRT2

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