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Q.

Which of the following salt solution gives white precipitate turning to black on adding HgCI2 solution?

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a

SnCl2

b

CuCl2

c

PbCl2

d

ZnCO3

answer is A.

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Detailed Solution

SnCl2 salt solution gives white precipitate turning to black on adding HgCI2 solution

SnCl2 is a powerful reducing agent that decreases

 Hg2CI2 to  HgCI2

(white), which is then further broken down to Hg (grey).
Following are the responses:

SnCl2+HgCl2SnCl4+Hg2Cl2SnCl2+Hg2Cl2SnCl4+2Hg

Hence option A is correct

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