Q.

Which of the following samples of reducing agents is/are chemically equivalent to 25mL of 0.2 N KMnO4 to be reduced to Mn2+ and water?
 

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a

25 mL of 0.1M H2O2to be oxidized to H+and O2

b

50 mL of 0.1M H3AsO3 to be oxidized to H3AsO4

c

25 mL of 0.2M FeSO4 to be oxidized to Fe3+

d

25 mL of 0.1M SnCl2 to be oxidized to Sn4+
 

answer is A, C, D.

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Detailed Solution

The reducing agents is/are chemically equivalent to 25 mL of 0.2 N KMnO4 to be reduced to Mn2+ and water.

milli equivalent of KMnO4 

=25×0.2 =5

(a) 25×0.2×1        (b) 50×0.1×3

(c) 25×0.1×2        (d) 25×0.1×2

Hence, the correct option is a, c and d.

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