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Q.

Which of the following set of overlap cannot provideπ-bond formation?

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a

3d and 2p

b

3p and ls

c

2p and 2p

d

2p and 3p

answer is D.

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Detailed Solution

Since the s orbital by nature is spherical, π- bonds cannot be formed because it can only accomplish head-on overlap. 

Hence,3p and 1s set of overlap cannot provideπ-bond formation.

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