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Q.

Which of the following set of species are coloured as well as diamagnetic?

(P) Cl2 and Br2

{Q) [AgBr and AgI]

(R) Na2Fe(CN)5NO and FeH2O5NO3SO4

(S) Na2Fe(CN)5NO and Na4Fe(CN)5NOS

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a

P, Q, S

b

P, R, Q

c

P, Q, R, S

d

Q, R, S

answer is A.

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Detailed Solution

In case of Cl2 and Br2 LMCT takes place because of which it shows intense color, although it has no unpaired electrons for d-d transition, it is diamagnetic.

Hence correct option is A.

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Which of the following set of species are coloured as well as diamagnetic?(P) Cl2 and Br2{Q) [AgBr and AgI](R) Na2Fe(CN)5NO and FeH2O5NO3SO4(S) Na2Fe(CN)5NO and Na4Fe(CN)5NOS