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Q.

Which of the following set of species are  diamagnetic?

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a

S3,S8,S6

b

P4,N2,O2

c

O3,S3,S2

d

Na2ZnO2,KO2,ClO2

answer is A.

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Detailed Solution

Sulfur exists as the gaseous form S2, which has two unpaired electrons in an anti-bonding atomic structure similar to that of O2. It has a magnetic field.
Sulfur exists in a gaseous state, designated S8, which is diamagnetic. Additionally diamagnetic is S6.

S3,S6 and S8 all are diamagnetic.

 

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