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Q.

Which of the following sets have correctly matched each molecule or ion and its shape?    

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a

Tetrahedral    Trigonal pyramidal T-shaped Square planar 
SO42NF3ICl3XeF4

                                                         

b

Tetrahedral    Trigonal pyramidal T-shaped Square planar 
CH4BCl3NO3SO42

                                           

 

c

Tetrahedral    Trigonal pyramidal T-shaped Square planar 
CCl4PF3ICl3SF4

                                                            

d

Tetrahedral    Trigonal pyramidal T-shaped Square planar 
CH4NO3GaI3SnCl4

                                                         

answer is B.

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Detailed Solution

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SO42 : Central atom sp3  -hybridised hence tetrahedral.
NF3 : Nsp3  -hybridised with one lone pair hence pyramidal.
ICl3:  Isp3d -hybridised with two lone pair hence T-shaped.
XeF4:  Xesp3d2 -hybridised with two lone pairs hence square planar.

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