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Which of the following shall form an octahedral complex ?

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d⁸ (High spin)

d⁶ (High spin)

All

d⁴ (Low spin)

answer is D.

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Detailed Solution

Octahedral complexes either have d²sp³ hybridization or sp³d² hybridization.

In d⁴ (low spin), unpaired electrons are paired in t_2gand two d-orbitals are empty in e_g which involve in an octahedral complex formation, d²sp³

In d⁸ (high spin) and d⁶ (high spin), they also form octahedral complexes that has sp³d² hybridization.

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