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Q.

Which of the following solid salt on heating with solid K2Cr2O7 and conc. H2SO4 orange red vapours are evolved which turn aquous NaOH solution yellow ?

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a

NaI

b

NaNO3

c

NaBr

d

NaCl

answer is B.

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Detailed Solution

NaCl(s)+K2Cr2O7(s)+H2SO4 (few drops) reactionNon-redox CrO2Cl2(orange red vapours)+HO

When CrO2Cl2 is treated with NaOH, then it forms a yellow color solution.
CrO2Cl2+OH(aq.)CrO4(aq.)2Yellow solution+Cl+2H2O

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Which of the following solid salt on heating with solid K2Cr2O7 and conc. H2SO4 orange red vapours are evolved which turn aquous NaOH solution yellow ?