Q.

Which of the following solution can form minimum boiling point azeotrope

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a

C2H5OH+H2O

b

n-heptane + n-hexane 

c

CH3COOH+C5H5N

d

C2H5Br+C2H5I

answer is A.

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Detailed Solution

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Minimum azeotropic mixture are those that boil at low temperature than they boil at pure state. Consequently, vapor pressure of the mixture is higher with respect to their pure components.

95.5%-ethyl alcohol and 4.5%-water forms a minimum azeotropic mixture.

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Which of the following solution can form minimum boiling point azeotrope