Which of the following solution can form minimum boiling point azeotrope

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n-heptane + n-hexane

$C_{2} H_{5} OH + H_{2} O$

$C_{2} H_{5} Br + C_{2} H_{5} I$

${CH}_{3} COOH + C_{5} H_{5} N$

answer is A.

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Detailed Solution

Minimum azeotropic mixture are those that boil at low temperature than they boil at pure state. Consequently, vapor pressure of the mixture is higher with respect to their pure components.

95.5%-ethyl alcohol and 4.5%-water forms a minimum azeotropic mixture.

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