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Which of the following solution requires three moles of AgNO₃ for the complete precipitation of all the chloride ions present in it

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One liter of 1M $[C o {({NH}_{3})}_{6}] {Cl}_{3}$

Three liters of 1M $[C o {({NH}_{3})}_{4} {Cl}_{2}] Cl$

One liter of 1.5 M $[Co {({NH}_{3})}_{5} C l] C l_{2}$

All the above

answer is A.

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Detailed Solution

$[Co {({NH}_{3})}_{6}] {Cl}_{3} \to {[Co {({NH}_{3})}_{6}]}^{3 +} + 3 {Cl}^{-}$

∴ three chlorides ions reacts with three moles AgNO₃ to form AgCl.

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