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Q.

Which of the following solutions is expected to show negative deviations from Raoult's law?

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a

Ethanol-water

b

Acetone-chloroform

c

 Ethanol-hexane

d

Ethyl ether-acetone 

answer is C.

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Detailed Solution

The intermolecular interactions in (A - B) are more powerful than those in (A - A) and (B - B).
For instance, acetone and chloroform combine to generate an impractical solution that deviates negatively from Raoult's law.
The volume of the solution is smaller than that of the solute and the solvent.

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