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Q.

Which of the following solutions will have pH close to 1.0?

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a

100ml of (M/10)HCl+100ml of (M/10) NaOH

b

55ml of (M/10)HCl+45ml of (M/10) NaOH

c

10ml of (M/10)HCl+90ml of (M/10)NaOH

d

75ml of (M/5)HCl+25ml of (M/5)NaOH

answer is D.

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Detailed Solution

100ml of HCl will completely neutralize 100ml of NaOH. So (A) is not possible, (C) will become a basic solution,(D) is the correct option.
25ml HCl neutralizes 25ml NaOH 
Remaining solution contains 50ml of M5HCl
Which becomes 100ml of M5HCl (as the total solution becomes 100ml)
pH=log[H+]=log[110]=1

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