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Q.

Which of the following species are correctly matched with their geometries according to the VSERR theory?

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a

BrF6+ octahedral 

b

SnCl5 trigonal bipyramidal 

c

ClF2 linear 

d

DF4+ see  saw 

answer is A, B, C, D.

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Detailed Solution

The number of total electrons surrounding the center atom is determined by the Lewis dot structure, in accordance with VSEPR theory multiple bonds (double/triple) count as one.
The geometry of electron pairs and the molecular geometry are determined by the number of bonding and non-bonding electron pairs.

Hence, BrF6+ octahedral according to the VSERR theory.

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