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Q.

Which of the following species are pyramidal in shape?  

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a

XeO3

b

ClF3

c

NH3

d

XeF4

answer is A, B.

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Detailed Solution

ClF3T-shaped The three hydrogen atoms and an unshared pair of electrons connected to the nitrogen atom form the trigonal pyramidal geometry of the ammonia molecule.
The molecule XeO3 will exhibit lone pair-bond pair repulsion as a result of the existence of a lone pair on the central atom, Xenon. In order to create pyramidal geometry, the trigonal planar geometry will be distorted.

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