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Q.

Which of the following species can act as reducing agent ?

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a

Mn(CO)6

b

Mn(CO)5

c

Co(CO)4

d

Cr(CO)6

answer is B.

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Detailed Solution

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Mn(CO)6 can act as reducing agent because the metal corbonyl is stable when EAN is equal to nearest noble gas configuration.
Mn(CO)6[ Less stable ) EAN =37eMn(CO)6 EAN =36 (More stable) 

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