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Which of the following species given below have shape similar to ${XeOF}_{4}$ ?

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${XeO}_{2}$

${PCl}_{5}$

${IOF}_{4}^{+}$

${XeF}_{5}^{\oplus}$

answer is D.

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Detailed Solution

${XeOF}_{4}$ (Xenon oxytetrafluoride) have shapes similar to ${XeF}_{5}^{\oplus}$ (bipyramidal pentagonal).

Due to the two and three lone pairs that the oxygen and fluorine atoms have, respectively, the xenon-oxygen double bonds also have a repelling effect. In order to minimize repulsive interactions,

Xe-F bonds are arranged in a plane, which is surrounded on two sides by oxygen atoms and lone pairs. The square pyramidal is the proper response.

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