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Q.

Which of the following species has / have axial $A - F$ bond length longer than equatorial $A - F$ bond length (where A is the central atom)?

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a

${PCl}_{2} F_{3}$

b

${ClF}_{3}$

c

All of these

d

${SF}_{4}$

answer is D.

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Detailed Solution

The has / have axial $A - F$ bond length is longer than equatorial $A - F$ bond length because of greater repulsion from equatorial bonds.

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