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Which of the following species represent the example of $d s p^{2}$ - hybridization?

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${[F e {(C N)}_{6}]}^{3 -}$

${[N i {(C N)}_{4}]}^{2 -}$

${[F e F_{6}]}^{3 -}$

${[Z n {(N H_{3})}_{4}]}^{2 +}$

answer is B.

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Detailed Solution

In ${[Ni {(CN)}_{4}]}^{2 -},$ Ni is in +2 oxidation state. As CN^- is a strong ligand, therefore pairing of electrons in 3d takes place. Therefore, a low spin complex forms with $d s p^{2}$ hybridization.

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