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Q.

Which of the following statement about the pyranose form of mannose is not correct?

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a

It reacts with Tollens’ reagent to give a silver mirror. (i.e., it is a reducing sugars).

b

Reaction with excess CH3I and AgOH gives a non-reducing penta–O–methyl derivative.

c

It resist reduction with aqueous sodium borohydride

d

It exists as two anomeric stereoisomers.

answer is D.

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Detailed Solution

Monosaccharides

  1. mannose exists as two anomeric stereoisomers
  2. mannose reacts with Tollens’ reagent to give a silver mirror. (i.e., it is a reducing sugars).
  3. Reaction with excess CH3I and AgOH gives a non-reducing Penta–O–methyl derivative.
  4. mannose reduction with aqueous sodium borohydride
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