Which of the following statement concerning probability density (${\mathrm{\psi }}^2$) and radial distribution function (4$\mathrm{\pi }$r²${\mathrm{\psi }}^2$) for a s-orbital of H-like species is correct?

Both ${\mathrm{\psi }}^2$ and 4${\mathrm{\pi r}}^2$ ${\mathrm{\psi }}^2$ are maximum at nucleus.

Both ${\mathrm{\psi }}^2$ and 4${\mathrm{\pi r}}^2$ ${\mathrm{\psi }}^2$ are minimum at nucleus.

${\mathrm{\psi }}^2$ is minimum at nucleus but 4${\mathrm{\pi r}}^2$ ${\mathrm{\psi }}^2$ is maximum at nucleus

${\mathrm{\psi }}^2$ is maximum at nucleus but 4${\mathrm{\pi r}}^2$ ${\mathrm{\psi }}^2$ is minimum at nucleus.