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Q.

Which of the following statement correct for the complex K4[Fe(CN)5 O2] having t2g6 , eg electronic configuration.

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a

d2sp3 hybridised and diamagnetic

b

sp3d2 hybridised and paramagnetic

c

sp3d2 hybridised and diamagnetic

d

d2sp3 hybridised and paramagnetic

answer is D.

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Detailed Solution

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Complex is paramagnetic due to presence of unpaired electron at O2- i.e superoxide acting as ligand.

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