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Q.

Which of the following statement is/are correct?

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a

O2  is paramagnetic, N2  is also paramagnetic

b

O2  is paramagnetic, N2  is diamagnetic

c

O2  is paramagnetic, O22  is also paramagnetic

d

In O2O2+  and  NONO+, bond length decreases.

answer is B, D.

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Detailed Solution

O2 is paramagnetic due to 2 unpaired electrons while N2&O22  are diamagnetic. In conversion of  O2&O2+ and NONO+ ,  e  from antibonding orbital (CN,N2,NO+,C22)  is removed, thus bond order increases & bond length decreases.

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