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Which of the following statement is correct?

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The square planar complex of general formulae ${Ma}_{3} b$ or ${Mab}_{3}$ exhibits cis-trans isomerism

The platinum glycinato complex, $[Pt (gly)_{2}]$ do not show geometrical isomerism

Geometrical isomerism is not observed in complexes of coordination number 4 having tetrahedral geometry

Square planar complexes generally do not show geometrical isomerism

answer is A.

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Detailed Solution

Geometrical isomerism is not observed in complexes of coordination number 4 having tetrahedral geometry. Because the unidentate ligands attached to the central metal atom have the same relative positions with respect to each other.

Thus, the correct answer is A.

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