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Q.

Which of the following statement is correct? 

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a

The square planar complex of general formulae Ma3b or Mab3 exhibits cis-trans isomerism 

b

The platinum glycinato complex,Pt(gly)2 do not show geometrical isomerism

c

Geometrical isomerism is not observed in complexes of coordination number 4 having tetrahedral geometry

d

 Square planar complexes generally do not show geometrical isomerism 

answer is A.

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Detailed Solution

Geometrical isomerism is not observed in complexes of coordination number 4 having tetrahedral geometry. Because the unidentate ligands attached to the central metal atom have the same relative positions with respect to each other.

Thus, the correct answer is A.

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