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Q.

Which of the following statement is correct for the following complex.[Fe(H2O)5NO]SO4

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a

The E.A.N value of Fe in this complex depends on the charge of 

NO ligand.

b

The E.A.N value of Fe in this complex does not depends on the charge of 

NO ligand.

c

It is paramagnetic with μ = 1.73 B.M

d

The hybridisation of the central atom is d2sp3

answer is B.

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Detailed Solution

FeI(H2O)5(N+O)]++     Hybridisation : sp3d2

                                    μeff : 3.89 BM

                                    Inspite of electronic transistion from NO to Fe++ ,total number of electrons remain conserved. Hence E.A.N does not change.

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