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Q.

Which of the following statement is correct for the reactivity in SN2 reaction?

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a

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b

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c

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d

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answer is B.

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Detailed Solution

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The electro negativity order of hybridized carbons is sp>sp2>sp3 . So in an allylic halide, such as CH2=CHCH2I , the alpha carbon is much more partially positive than the alpha carbon in CH3CH2CH2I .Therefore, the attacking nucleophile will be attracted to the alpha carbon more in the allylic halide compound than in the primary halide. Hence, allylic halides tend to follow SN2 pathways more than primary halides.

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