Q.

Which of the following statement is correct in relation to the halogenation of alkane ?

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a

Bromine has much higher regioselectivity than chlorine in abstracting 30 hydrogen.

b

Photochemical chlorination of methane is formed in slowest step.

c

Free radicals are pyramidal intermediate, stabilised by hyperconjugation and resonance.

d

The reactivity of chlorine is less than bromine towards alkanes. 

answer is D.

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Detailed Solution

Bromine atom has a much higher regioselectivity than chlorine atom in abstracting 30 hydrogen.

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