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Q.

Which of the following statement is false?

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a

NiCl42 ion is paramagnetic and tetrahedral but PtCl42 is diamagnetic and square planar

b

CoF63 ion is paramagnetic but NiF62 ion is diamagnetic and low spin

c

Δ0 order CrCl63<CrNH363+<Cr(CN)63

d

bis(dime thy lglyoximato )nickel(II) is diamagnetic and tetrahedral complex

answer is D.

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Detailed Solution

Since Ni(DMG)2 ( bis( dimethylglyoximato )nickel(II)) is square planar and dsp2.

Option D is incorrect.

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