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Q.

Which of the following statement is incorrect?

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a

XeF6(s) is found to be ionic solid consisting of  XeF5+ and F ions.

b

FeSO47H2O and MgSO47H2O are isomorphous to each other.

c

Transition metals may use inner- d-electrons along with the outer electrons for metallic bonding as (n1)d and ns have nearly same energy. Hence, their melting points are higher.

d

Chloral hydrate shows intermolecular hydrogen bonding.

answer is D.

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Detailed Solution

The electron density of chlorine, which is a result of the size of its atom, prevents it from exhibiting hydrogen bonding. Despite having a strong electronegative charge, chlorine does not generate intramolecular or intermolecular hydrogen bonds.

Chloral hydrate shows intramolecular hydrogen bonding statement is incorrect.

Hence, option D is correct.

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