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Q.

Which of the following statement is incorrect?

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a

The conversion of primary aromatic amines into diazonium salt is known as diazotisation

b

Diazonium salt is not generally stored, used immediately after its preparation

c

Benzenediazonium chloride is prepared by the reaction of aniline with nitrous acid at 273-278 K 

d

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answer is B.

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Detailed Solution

Benzene diazonium chloride is prepared by the reaction of aniline with nitrous acid at 273-278 K which is known as diazotisation.
Due to its instability, the diazonium salt is not generally stored and is used immediately after its preparation.
C6H5NH2+NaNO2+2HCI273-278 KC6H5N2+Cl-+NaCl+2H2O
Temperature must vary from 0-5oc.

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