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Q.

Which of the following statement is incorrect?

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a

It is possible to separate eclipsed and staggered form of ethane at room temperature

b

Eclipsed form has torsional strain

c

Energy difference between staggered form & eclipsed form of ethane is 12.5 kJ/mole

d

Ethane has infinite number of conformers

answer is A.

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Detailed Solution

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Not possible due to free rotation around bond.

The energy differences between staggered and eclipsed froms of ethane is just `12.55 "kJ mol"^(-1)` which is easily met by collisions of the molecules at room temperature. Therefore, it is not possible to isolate either pure staggered or pure eclipsed ethane at room temperature

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