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Which of the following statement is wrong for solvay process

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NH₃ is regenerated

CaCl₂ is one of the by product

CaCO₃ is used completely in reaction

Na₂CO₃ is partially converted into bicarbonate

answer is D.

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Detailed Solution

2NH₃ + CO₂ + H₂O → [NH₄]₂CO₃
[NH₄]₂CO₃ + H₂O + CO₂ → 2NH₄HCO₃
NH₄HCO₃ + NaCl → NH₄Cl + NaHCO₃
2NaHCO₃ → Na₂CO₃ +CO₂ + H₂O
regeneration of NH₃ :

$2 {NH}_{4} Cl + Ca {(OH)}_{2} \to 2 {NH}_{3} + \underset{Byproduct}{{CaCl}_{2}}$

Na₂CO₃ can't converted into bicarbonate on heating

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