Q.

Which of the following statement(s) is/are correct regarding the halides of group 15  elements?

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a

Trihalides except  BiF3  are predominantly covalent in nature.

b

POCl3  is obtained as one of the intermediate product during the hydrolysis of  PCl5

c

PCl3  hydrolyses in the presence of moisture giving fumes of HCl

d

Solid  PCl5  exists as [PCl4]+[PCl6] 

answer is A, B, C, D.

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Detailed Solution

Ans: ABCD
Sol:  (i)PCl5+H2OPOCl3+2HCl
 (ii)PCl3+H2OH3PO3+HCl
 (iii)PCl4+      PCl6

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Which of the following statement(s) is/are correct regarding the halides of group 15  elements?