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Q.

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Which of the following statement(s) is/are correct?

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a

I and II are aromatic, but I is more basic than III

b

I is anti-aromatic, II is aromatic and II is more basic than I

c

The order of basicity of above compounds is IV > III > II > I

d

The conjugate acid of II is less stabilized than conjugate acid of IV

answer is C, D.

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Detailed Solution

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The correct order of basicity is 
 (IV)>(III)>(II)>(I)

In IV , lone pair of two N makes it more basic and does not delocalize in the benzene ring. 
A compound is more basic, if its conjugate acid can be stabilized through resonance.

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