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Q.

Which of the following statement(s) is/are correct?

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a

Permanganate ion, pertechnate ion and perrhenate ion are all dark purple coloured species

b

In both haemoglobin and oxyhaemoglobin, iron is in +2 oxidation state

c

Both [Ni(CO)4] and [NiCl4]2 are tetrahedral complexes

d

Chromium form highly oxidizing compounds in +6 oxidation state, whereas the equivalent compounds of molybdenum and tungsten are not appreciably oxidizing

answer is B, C, D.

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Detailed Solution

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MnO4 - coloured; TcO4 and ReO4 are colourless as the energy required for the charge transfer process corresponds to absorption in the UV.

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Which of the following statement(s) is/are correct?