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Q.

Which of the following statement(s) is/are correct?

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a

Formation of  Mg(g)2+ from Mg(g) and  O(g)2  from O(g) are endothermic but the formation of  MgO(s) from  Mg(g)2+ and  O(g)2  is exothermic

b

Reaction  Pb3O4+8HCl3PbCl2+Cl2+4H2O involves both acid – base reaction  and redox reaction

c

When  BCl3 gas is passed into an aq solution of NaCl, Boric acid is formed

d

Alkali metal hydroxides are more corrosive than alkaline earth metal hydroxides

answer is A, B, C, D.

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Detailed Solution

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 i)  2PbO+4HCl2PbCl2+2H2O  and  PbO2+4HClPbCl2+Cl2+2H2O
(ii)  Mg(g)Mg(g)2+,ΔH=+ve
 O(g)O(g)2,ΔH=+ve
Mg(g)2++O(g)2MgO(s),ΔH=ve

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