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Q.

Which of the following statement(s) is/are false?

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a

ΔrS  for12Cl2(g)Cl(g) is positive

b

ΔE<0 for combustion ofCH4(g)  in a sealed container with rigid adiabatic system.

c

ΔG is always zero for a reversible process in a closed system

d

ΔG for an ideal gas reaction is a function of pressure

answer is B, C, D.

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Detailed Solution

A)Cl2(g)2Cl(g)  randomness is increasing
B) In closed container ΔV=0  hence work done is zero
There is no heat exchange Hence ΔE=q+W=0
C) ΔG will be zero only when equilibrium is reached false statement
D) ΔG°=RT  ln  Keq not a function of pressure
 

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Which of the following statement(s) is/are false?