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Q.

Which of the following statement(s) is/are incorrect?
1) Boron shows +1 and +3 oxidation states
2) Sn+2 is more stable than Sn+4 
3) Tl+3 is more stable than Tl+1 due to inert pair effect
4) Pb+4 is a stronger oxidising agent than Pb+2

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a

1, 3 and 4

b

1, 2 and 3

c

1, 2 and 4

d

1, 2, 3 and 4

answer is B.

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Detailed Solution

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a) Due to small size of boron, the sum of it’s first three ionization enthalpie’s is very high
b) This preent is it to form +3 ion's
c) As we move down in group 13, due to inert pair effect the tendency to exhibit + 3 oxidation state decreases
d) The compounds in +2, Oxidation state are covalent in nature (fajan rule)

 

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