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Q.

Which of the following statement(s) is/are true?

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a

ΔfHo  (S, monoclinic) 0

b

If  ΔHf(H2O,g)= - 242 kJ/mol; ΔHvap (H2O,l ) = 44kJ/mol then, ΔfHo(OH,aq.) will be – 142 kJ/ mol

c

Combustion of hydrocarbons are generally an exothermic process

d

If dissociation energy ofCH4(g)  is 1656 kJ/mol and C2H6(g) is 2812 kJ/mol, then value of C – C bond energy will be 328 kJ/mol

answer is A, B, C.

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Detailed Solution

(a)  ΔE=q+W=0+0=0
(b) (ΔFHo) (S, rhombic) = 0
(c) (C – C) + (C – H) = 2812
   (CC)=28126×16564=328   
(d)  H2O(l)H2O(g)
              44 = - (ΔFH)H2O(l)242
 (ΔFH)H2O(l)286
 H+(aq)+OH(aq)H2O(l)
  57.3=2864(ΔfH)OH=228.7

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Which of the following statement(s) is/are true?