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Q.

Which of the following statement(s) is/are true about the complex ion [Pt (en)2 Cl2]2+ ?
[en = H2N CH2 CH2 NH2]

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a

The oxidation state of Pt in the complex is +4

b

Only the cis isomer has non-superimposable mirror image

c

It has two geometrical isomers-cis and trans

d

Both the cis and trans isomers display optical activity

answer is A, C, D.

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Detailed Solution

Let oxidation number of Pt = x
1 x x +2 x 0 + 2 x (-1) = +2
x = +4
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