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Q.

Which of the following statement (s) is/are correct among the options given.

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a

pOH of an acidic buffer decreases if less salt is added

b

pOH of a basic buffer decreases if less salt is added

c

At the saturation point the ionic product is equal to solubility product

d

The term solubility product is only for sparingly soluble salt

answer is A, B, C.

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Detailed Solution

pH=pKa+log[ Salt ][ Acid ], pOH=pKb+log[ Salt ] [Base ]

Thus as salt concentration decreases for acidic buffers, so pH decreases. Statement (a) is correct, Thus as salt  decreases, Choice (b) is correct. For any salt when Q=Ksp

Hence the solution is saturated. Hence choice (c) is correct.

The solubility product is for all salts. choice (d) is Incorrect.

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