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Q.

Which of the following statement(s) regarding molecular orbital (MO) theory is/are correct?

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a

Pairing of electrons during the formation of a molecule is not a necessary condition unlike valence bond (VB) theory

b

In C22ion, there is one sigma bond and 2 pi bonds.

c

Li2 molecule contain one sigma bond while B2 molecule contain 1 πbond.

d

Both H2 and Li2 have one sigma bond each but the sigma bond in H2 is stronger than in Li2.

answer is A, B, C, D.

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Detailed Solution

Pairing of electrons during the formation of a molecule is not necessary unlike VB theory as in O2,B2, etc. Dicarbide ion has one sigma and two pi bonds.

Electronic configuration of B2 is σ1s2σ*1s2σ2s2σ*2s2π2px1=π2px1

Electronic configuration of Li2 is σ1s2σ*1s2σ2s2

Bond energy of H2is more than Li2 due to small size of H-atom.

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